| Abstract: | The ion-activity product of water, KW0, has been determined to 350?? along the liquid-vapor curve from conductance measurements made between 100 and 350?? on aqueous solutions in the system acetic acid-ammonium acetate-ammonia. Derivation of KW0 requires data on the limiting equivalent conductivities of acetic acid, ammonia, and ammonium acetate, the ionization constants of acetic acid and ammonia, and of the conductivities of pairs of these solutes at a series of concentrations. The limiting equivalent conductivities were indirectly obtained from literature data on the limiting equivalent conductivities of HCl, NaCl, NaOH, NH4Cl, and NaOAc. The ionization constants of acetic acid were obtained from our conductance measurements combined with literature data; constants for ammonia were obtained from the literature. From our conductivities, values of KW0 were obtained between 100 and 350??; these were combined with well established literature values and the combined set analytically smoothed to provide a consistent set of molal constants from 25 to 350??; respective pK‘s at 150, 250, and 350?? are: for H2O, 11.64, 11.05, and 11.42; for HOAc, 5.22, 5.95, and 7.68; and for NH4OH, 5.11, 5.91, and 7.30. |
| Genre: | Article |
| ProdID: | 70010141 |
| Citation Author: | Fisher, J. R.; Barnes, H. L. |
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| Citation End Page: | 99 |
| Citation Issue: | 1 |
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| Citation Language: | English |
| Citation Larger Work Title: | Journal of Physical Chemistry |
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| Citation Number Of Pages: | 10 |
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| Citation Publisher: | American Chemical Society |
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| Citation Search Results Text: | he Ion-Product Constant of Water to 350°; 1972; Article; Journal; Journal of Physical Chemistry; Fisher, J. R.; Barnes, H. L. |
| Citation Start Page: | 90 |
| Citation Volume: | 76 |
| Citation Year: | 1972 |
| Type: | citation/reference |
| Text: | he Ion-Product Constant of Water to 350°; 1972; Article; Journal; Journal of Physical Chemistry; Fisher, J. R.; Barnes, H. L. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| URL (DIGITAL OBJECT IDENTIFIER): | http://dx.doi.org/10.1021/j100645a016 |
| Date Other: | Sat, 1 Jan 1972 00:00 -0600 |
| Publisher: | American Chemical Society |
