Analyses of rim-to-interior samples of fresh tholeiitic pillow basalts, deuterically altered holocrystalline basalts, and older, weathered tholeiitic basalts from the deep sea indicate that 87Sr 86Sr ratios of the older basalts are raised by low temperature interaction with strontium dissolved in sea water. 87Sr 86Sr correlates positively with H2O in these basalts; however, there is little detectable modification of the strontium isotope composition in rocks with H2O contents less than 1%. The isotope changes appear to be a function of relatively long-term, low-temperature weathering, rather than high-temperature or deuteric alteration. Strontium abundance and isotopic data for these rocks suggest that strontium content is only slightly modified by interaction with sea water, and it is a relatively insensitive indicator of marine alteration. Average Rb-Sr parameters for samples of apparently unaltered basalt are: Rb = 1.11 ppm; Sr = 132 ppm; 87Sr 86Sr = 0.70247. ?? 1973.
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Effect of sea water interaction on strontium isotope composition of deep-sea basalts