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Aromatic fluorine compounds. VII. Replacement of aromatic -Cl and -NO2 groups by -F

Journal of the American Chemical Society

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Abstract

Replacement of -Cl by -F in aryl chlorides with potassium fluoride has been extended from 2,4-dinitrochlorobenzene to less activated halides by the use of non-aqueous solvents, especially dimethylformamide (DMF) and dimethyl sulfoxide (DMSO). Also replacement of -NO2 by -F in substituted nitrobenzenes was studied in DMF. As a direct result of this study, many aromatic fluorine compounds can now be obtained by a relatively simple synthetic route.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Aromatic fluorine compounds. VII. Replacement of aromatic -Cl and -NO2 groups by -F
Series title:
Journal of the American Chemical Society
Volume
78
Issue:
23
Year Published:
1956
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Journal of the American Chemical Society
First page:
6034
Last page:
6037