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Manganese complexes with bicarbonate and sulfate in natural water

Journal of Chemical and Engineering Data

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Abstract

The association constant for the dissolved species MnHCO3+ was experimentally determined to be 63. From this value and a published constant for the species MNSO4 aq., a diagram was prepared showing per cent of dissolved manganese complexed in the presence of 10 to 10,000 p.p.m. bicarbonate and 1.0 to 10,000 p.p.m. sulfate. The rate of oxidation of Mn+2 in aerated water is greatly increased by increasing pH, and is retarded when SO4-2and HCO3- are present.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Manganese complexes with bicarbonate and sulfate in natural water
Series title:
Journal of Chemical and Engineering Data
Volume
8
Issue:
1
Year Published:
1963
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Journal of Chemical and Engineering Data
First page:
99
Last page:
101