Infrared spectral behavior of fine particulate solids

Journal of Physical Chemistry
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Abstract

Transmission and emission spectra of clouds and layers of fine particulate samples of quartz, magnesium oxide, and aluminum oxide in the 6.5-35-??m wavelength range are presented. They demonstrate that the behavior of layers of particles constitutes a good analogue for a cloud of particles; that individual micrometer-sized particles emit most where they absorb most; that as the size of the particle is increased, the emission features reverse polarity and the spectrum approaches that of one obtained from a polished plate; and that as the particle layer-thickness increases, radiative interaction becomes increasingly important so that the emission maximum shifts from the strongest to weaker features, or produces a maximum at the Christiansen wavelength.
Publication type Article
Publication Subtype Journal Article
Title Infrared spectral behavior of fine particulate solids
Series title Journal of Physical Chemistry
DOI 10.1021/j100552a015
Volume 80
Issue 11
Year Published 1976
Language English
Larger Work Type Article
Larger Work Subtype Journal Article
Larger Work Title Journal of Physical Chemistry
First page 1195
Last page 1198
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