| Abstract: | The heat capacity of a hydrothermally-prepared polycrystalline sample of Fe3O4 was measured from 53 to 350 K, primarily to study the thermophysics of the Verwey transitions. Although the bifurcation of the transition was confirmed, the sample was found to contain traces of manganese. The observed transition temperatures of 117.0 and 123.0 K are 3.7 and 4.2 K higher respectively than those found in pure Fe3O4. Ancillary analytical results are consistent and indicate a stoichiometry of Mn0.008Fe2.992O4 for this material. Characteristics in the transition region are ascribed to dopant effects. ?? 1976. |
| Genre: | Article |
| ProdID: | 70011106 |
| Citation Author: | Bartel, J. J.; Westrum, Jr. , E. F.; Haas, Jr. , J. L. |
| Citation Contributing Office: | |
| Citation Datum: | |
| Citation Day: | |
| Citation Edition: | |
| Citation Editor: | |
| Citation End Page: | 581 |
| Citation Issue: | 6 |
| Citation Keywords: | |
| Citation Language: | English |
| Citation Larger Work Title: | Journal of Chemical Thermodynamics |
| Citation LatN: | |
| Citation LatS: | |
| Citation LonE: | |
| Citation LonW: | |
| Citation Month: | |
| Citation No Pagination: | |
| Citation Number Of Pages: | 7 |
| Citation Online Only Flag: | |
| Citation Phsyical Description: | |
| Citation Projection: | |
| Citation Public Comments: | |
| Citation Publisher: | Elseveir |
| Citation Series: | |
| Citation Series Code: | |
| Citation Series Number: | |
| Citation Search Results Text: | Thermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4; 1976; Article; Journal; Journal of Chemical Thermodynamics; Bartel, J. J.; Westrum, Jr. , E. F.; Haas, Jr. , J. L. |
| Citation Start Page: | 575 |
| Citation Volume: | 8 |
| Citation Year: | 1976 |
| Type: | citation/reference |
| Text: | Thermodynamics of Fe(II)Fe(III) oxide systems I. Hydrothermal Fe3O4; 1976; Article; Journal; Journal of Chemical Thermodynamics; Bartel, J. J.; Westrum, Jr. , E. F.; Haas, Jr. , J. L. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| URL (DIGITAL OBJECT IDENTIFIER): | http://dx.doi.org/10.1016/0021-9614(76)90031-8 |
| Date Other: | Thu, 1 Jan 1976 00:00 -0600 |
| Publisher: | Elseveir |
