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Alternate drop pulse polarography

Analytical Chemistry

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, , and

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Abstract

The new technique of alternate drop pulse polarography is presented. An experimental evaluation of alternate drop pulse polarography shows complete compensation of the capacitative background due to drop expansion. The capillary response phenomenon was studied in the absence of faradaic reaction and the capillary response current was found to depend on the pulse width to the -0.72 power. Increased signal-to-noise ratios were obtained using alternate drop pulse polarography at shorter drop times.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Alternate drop pulse polarography
Series title:
Analytical Chemistry
Volume
48
Issue:
2
Year Published:
1976
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Analytical Chemistry
First page:
242
Last page:
247
Number of Pages:
6