Alternate drop pulse polarography
Analytical Chemistry
By: J. H. Christie, Larry L. Jackson, and R. A. Osteryoung
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Abstract
The new technique of alternate drop pulse polarography is presented. An experimental evaluation of alternate drop pulse polarography shows complete compensation of the capacitative background due to drop expansion. The capillary response phenomenon was studied in the absence of faradaic reaction and the capillary response current was found to depend on the pulse width to the -0.72 power. Increased signal-to-noise ratios were obtained using alternate drop pulse polarography at shorter drop times.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Alternate drop pulse polarography |
| Series title | Analytical Chemistry |
| DOI | 10.1021/ac60366a002 |
| Volume | 48 |
| Issue | 2 |
| Year Published | 1976 |
| Language | English |
| Publisher | ACS Publications |
| Description | 6 p. |
| First page | 242 |
| Last page | 247 |
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