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Laser induced fluorescence spectra of fluorophenol cations in a Ne matrix

Journal of Chemical Physics

By:
, , , and
DOI: 10.1063/1.445067

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Abstract

Laser induced fluorescence and/or absorption spectra of the cations of 2,3,5,6‐tetrafluorophenol, 2,3,5,6‐tetrafluorothiophenol, and 3,5‐difluorophenol have been obtained in a Ne matrix. The spectra of C6HF4OH+ are much better resolved than in the gas phase. The gas phase congestion is likely caused by the near degeneracy of the and electronic states whose separation is now measured at 207 cm−1. The spectrum of C6H3F2OH+ represents a deperturbed example of the Jahn–Teller distorted sym‐C6F3H3+ ion. C6H3F2SH+ shows only a broad featureless absorption.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Laser induced fluorescence spectra of fluorophenol cations in a Ne matrix
Series title:
Journal of Chemical Physics
DOI:
10.1063/1.445067
Volume
78
Issue:
5
Year Published:
1983
Language:
English
Publisher:
American Institute of Physics
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Journal of Chemical Physics
First page:
2227
Last page:
2230
Number of Pages:
4