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Separation of arsenic(III) and arsenic(V) in ground waters by ion-exchange

Talanta

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Abstract

The predominant species of arsenic in ground water are probably arsenite and arsenate. These can be separated with a strong anion-exchange resin (Dowex 1 ?? 8; 100-200 mesh, acetate form) in a 10 cm ?? 7 mm column. Samples are filtered and acidified with concentrated hydrochloric acid (1 ml per 100 ml of sample) at the sample site. Five ml of the acidified sample are used for the separation. At this acidity, As(III) passes through the acetate-form resin, and As(V) is retained. As(V) is eluted by passage of 0.12M hydrochloric acid through the column (resulting in conversion of the resin back into the chloride form). Samples are collected in 5-ml portions up to a total of 20 ml. The arsenic concentration in each portion is determined by graphite-furnace atomic-absorption spectrophotometry. The first two fractions give the As(III) concentration and the last two the As(V) concentration. The detection limit for the concentration of each species is 1 ??g l. ?? 1983.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Separation of arsenic(III) and arsenic(V) in ground waters by ion-exchange
Series title:
Talanta
Volume
30
Issue:
5
Year Published:
1983
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Talanta
First page:
371
Last page:
373