| Abstract: | A simple differential thermal analysis (DTA) technique has been developed to study phase relations of various chemical systems at elevated pressures and temperatures. The DTA system has been calibrated against known melting temperatures in the system NaCl-KCl. Isobaric sections of the liquidus in the system NaCl-KCl have been determined at pressures of 1 atmosphere and 500, 1000, 1500, and 2000 bars. Using the least-squares method, the following equation was used to fit the experimental data: T(??C)= ??? i=0 6aiXiKCl where T is the liquidus temperature, XKCl is mole fraction of KCl, and ai (listed below) are the derived empirical constants. {A table is presented}. The liquidus temperatures estimated from these equations are within ??3??C of experimental values. The measured liquidus temperatures at 1 atmosphere agree with the best available data to within 5??C. The melting temperatures for pure end members at higher pressures agree with the values calculated from the Simon equation (Clark, 1959) to within 3??C. No previous melting data are available for the intermediate compositions at elevated pressures. Using the data in both heating and cooling scans, the minimum melting temperature at 1 atmosphere in the system was located at 658?? ?? 3??C where the sample has an equimolar composition. ?? 1982. |
| Genre: | Article |
| ProdID: | 70011517 |
| Citation Author: | Chou, I. -M. |
| Citation Contributing Office: | |
| Citation Datum: | |
| Citation Day: | |
| Citation Edition: | |
| Citation Editor: | |
| Citation End Page: | 1962 |
| Citation Issue: | 10 |
| Citation Keywords: | |
| Citation Language: | English |
| Citation Larger Work Title: | Geochimica et Cosmochimica Acta |
| Citation LatN: | |
| Citation LatS: | |
| Citation LonE: | |
| Citation LonW: | |
| Citation Month: | |
| Citation No Pagination: | |
| Citation Number Of Pages: | 6 |
| Citation Online Only Flag: | |
| Citation Phsyical Description: | |
| Citation Projection: | |
| Citation Public Comments: | |
| Citation Publisher: | |
| Citation Series: | |
| Citation Series Code: | |
| Citation Series Number: | |
| Citation Search Results Text: | Phase relations in the system NaCl-KCl-H2O. Part I: Differential thermal analysis of the NaCl-KCl liquidas at 1 atmosphere and 500, 1000, 1500, and 2000 bars; 1982; Article; Journal; Geochimica et Cosmochimica Acta; Chou, I. -M. |
| Citation Start Page: | 1957 |
| Citation Volume: | 46 |
| Citation Year: | 1982 |
| Type: | citation/reference |
| Text: | Phase relations in the system NaCl-KCl-H2O. Part I: Differential thermal analysis of the NaCl-KCl liquidas at 1 atmosphere and 500, 1000, 1500, and 2000 bars; 1982; Article; Journal; Geochimica et Cosmochimica Acta; Chou, I. -M. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| Date Other: | Fri, 1 Jan 1982 00:00 -0600 |
| Publisher: | |
