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Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution

Journal of Chemical Physics

By:
, , , ,
DOI: 10.1063/1.441120

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Abstract

The absorption and laser induced fluorescence of several halogenated benzene radical cations were studied in solid Ne matrices. The spectra of 1,2,4-trifluorobenzene, l,3-dichloro-5-fluorobenzene, and l-chloro-3,5- difluorobenzene radical cations are observed and analyzed. Studies of fluorescence polarization and a photoselection technique were used to examine the splitting of the degeneracy of the benzene cation ground state by asymmetric subsitution. ?? 1981 American Institute of Physics.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Halogenated benzene radical cations and ground state degeneracy splitting by asymmetric substitution
Series title:
Journal of Chemical Physics
DOI:
10.1063/1.441120
Volume
74
Issue:
12
Year Published:
1981
Language:
English
Publisher:
American Institute of Physics
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
First page:
6584
Last page:
6591
Number of Pages:
8