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A routine high-precision method for Lu-Hf isotope geochemistry and chronology

Contributions to Mineralogy and Petrology

By:
and
DOI: 10.1007/BF01166766

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Abstract

A method for chemical separation of Lu and Hf from rock, meteorite and mineral samples is described, together with a much improved mass spectrometric running technique for Hf. This allows (i) geo- and cosmochronology using the176Lu???176Hf+??- decay scheme, and (ii) geochemical studies of planetary processes in the earth and moon. Chemical yields for the three-stage ion-exchange column procedure average 90% for Hf. Chemical blanks are <0.2 ng for Lu and Hf. From 1 ??g of Hf, a total ion current of 0.5??10-11 Ampere can be maintained for 3-5 h, yielding 0.01-0.03% precision on the ratio176Hf/177Hf. Normalisation to179Hf/177Hf=0.7325 is used. Extensive results for the Johnson Matthey Hf standard JMC 475 are presented, and this sample is urged as an international mass spectrometric standard; suitable aliquots, prepared from a single batch of JMC 475, are available from Denver. Lu-Hf analyses of the standard rocks BCR-1 and JB-1 are given. The potential of the Lu-Hf method in isotope geochemistry is assessed. ?? 1980 Springer-Verlag.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
A routine high-precision method for Lu-Hf isotope geochemistry and chronology
Series title:
Contributions to Mineralogy and Petrology
DOI:
10.1007/BF01166766
Volume
75
Issue:
3
Year Published:
1981
Language:
English
Publisher location:
Springer-Verlag
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Contributions to Mineralogy and Petrology
First page:
263
Last page:
267
Number of Pages:
5