Ne matrix spectra of the sym-C6Br3F3+ radical cation
Chemical Physics
By: V.E. Bondybey, T.J. Sears, T.A. Miller, C. Vaughn, J.H. English, and R.S. Shiley
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Abstract
The electronic absorption and laser excited, wavelength resolved fluorescence spectra of the title cation have been observed in solid Ne matrix and vibrationally analysed. The vibrational structure of the excited B2A2??? state shows close similarity to the parent compound. The X2E??? ground state structure is strongly perturbed and irregular owing to a large Jahn-Teller distortion. The data are analysed in terms of a recently developed, sophisticated multimode Jahn-Teller theoretical model. We have generated the sym-C6Br3F3+ cations in solid Ne matrix and obtained their wavelength resolved emission and absorption spectra. T ground electronic X2E??? state exhibits an irregular and strongly perturbed vibrational structure, which can be successfully modeled using sophisticated multimode Jahn-Teller theory. ?? 1981.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Ne matrix spectra of the sym-C6Br3F3+ radical cation |
| Series title | Chemical Physics |
| DOI | 10.1016/0301-0104(81)85043-4 |
| Volume | 61 |
| Issue | 1-2 |
| Year Published | 1981 |
| Language | English |
| Publisher | Elsevier |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Chemical Physics |
| First page | 9 |
| Last page | 16 |
| Google Analytic Metrics | Metrics page |