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Ne matrix spectra of the sym-C6Br3F3+ radical cation

Chemical Physics

By:
, , , , , and
DOI: 10.1016/0301-0104(81)85043-4

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Abstract

The electronic absorption and laser excited, wavelength resolved fluorescence spectra of the title cation have been observed in solid Ne matrix and vibrationally analysed. The vibrational structure of the excited B2A2??? state shows close similarity to the parent compound. The X2E??? ground state structure is strongly perturbed and irregular owing to a large Jahn-Teller distortion. The data are analysed in terms of a recently developed, sophisticated multimode Jahn-Teller theoretical model. We have generated the sym-C6Br3F3+ cations in solid Ne matrix and obtained their wavelength resolved emission and absorption spectra. T ground electronic X2E??? state exhibits an irregular and strongly perturbed vibrational structure, which can be successfully modeled using sophisticated multimode Jahn-Teller theory. ?? 1981.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Ne matrix spectra of the sym-C6Br3F3+ radical cation
Series title:
Chemical Physics
DOI:
10.1016/0301-0104(81)85043-4
Volume
61
Issue:
1-2
Year Published:
1981
Language:
English
Publisher:
Elsevier
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Chemical Physics
First page:
9
Last page:
16
Number of Pages:
8