| Abstract: | Emission spectra of the cations of 2,5- and 3,5-difluorophenol, of 2,3,4- and 2,4,5-trifluorophenol, of 2,3,5,6-tetrafluorophenol and of 2,3,4,5,6-pentafluorophenol have been obtained in the gas phase using low-energy electron beam excitation. The band systems are assigned to the B??(??-1) ??? X??(??-1) electronic transitions of these cations by reference to photoelectron spectroscopic data. The He(I??) photoelectron spectra and the ionisation energies of ten fluoro-substituted phenols are reported. The symmetries of the four lowest electronic states of these cations are inferred from the radiative decay studies. The lifetimes of the lowest vibrational levels of the B??(??-1) state of the six fluoro-substituted phenol cations above have also been measured. ?? 1980. |
| Genre: | Article |
| ProdID: | 70012199 |
| Citation Author: | Maier, J. P.; Marthaler, O.; Mohraz, M.; Shiley, R. H. |
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| Citation End Page: | 20 |
| Citation Issue: | 1 |
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| Citation Language: | English |
| Citation Larger Work Title: | Journal of Electron Spectroscopy and Related Phenomena |
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| Citation Number Of Pages: | 10 |
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| Citation Search Results Text: | Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase; 1980; Article; Journal; Journal of Electron Spectroscopy and Related Phenomena; Maier, J. P.; Marthaler, O.; Mohraz, M.; Shiley, R. H. |
| Citation Start Page: | 11 |
| Citation Volume: | 19 |
| Citation Year: | 1980 |
| Type: | citation/reference |
| Text: | Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase; 1980; Article; Journal; Journal of Electron Spectroscopy and Related Phenomena; Maier, J. P.; Marthaler, O.; Mohraz, M.; Shiley, R. H. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| Date Other: | Tue, 1 Jan 1980 00:00 -0600 |
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