thumbnail

Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase

Journal of Electron Spectroscopy and Related Phenomena

By:
, , ,

Links

  • The Publications Warehouse does not have links to digital versions of this publication at this time
  • Download citation as: RIS

Abstract

Emission spectra of the cations of 2,5- and 3,5-difluorophenol, of 2,3,4- and 2,4,5-trifluorophenol, of 2,3,5,6-tetrafluorophenol and of 2,3,4,5,6-pentafluorophenol have been obtained in the gas phase using low-energy electron beam excitation. The band systems are assigned to the B??(??-1) ??? X??(??-1) electronic transitions of these cations by reference to photoelectron spectroscopic data. The He(I??) photoelectron spectra and the ionisation energies of ten fluoro-substituted phenols are reported. The symmetries of the four lowest electronic states of these cations are inferred from the radiative decay studies. The lifetimes of the lowest vibrational levels of the B??(??-1) state of the six fluoro-substituted phenol cations above have also been measured. ?? 1980.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase
Series title:
Journal of Electron Spectroscopy and Related Phenomena
Volume
19
Issue:
1
Year Published:
1980
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Journal of Electron Spectroscopy and Related Phenomena
First page:
11
Last page:
20
Number of Pages:
10