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(π−1) → (π−1), (π−1) emission spectra of chlorofluorobenzene cations in the gaseous phase and their lifetimes in the (0o) states

Chemical Physics

By:
, , ,
DOI: 10.1016/0301-0104(80)85015-4

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Abstract

The radiative decay of seventeen electronically excited chlorofluorobenzene cations in the gaseous phase has been detected. The reported emission spectra, which have been obtained using low energy electron beam excitation, are assigned to the B(??-1 ??? X(??-1 electronic transitions of these cations on the basis of their Ne(I) photoelectron spectra. In another sixteen chloroflourobenzene cations, the B ??? X radiative decay could not be detected, from which is inferred that the B states are now associated with Cl 3p(??-1 ionisation processes. The lifetimes of the studied cations in the lowest vibrational levels of the B(??-1 state have been measured. ?? 1980.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
(π−1) → (π−1), (π−1) emission spectra of chlorofluorobenzene cations in the gaseous phase and their lifetimes in the (0o) states
Series title:
Chemical Physics
DOI:
10.1016/0301-0104(80)85015-4
Volume
47
Issue:
3
Year Published:
1980
Language:
English
Publisher:
Elsevier
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Chemical Physics
First page:
295
Last page:
305
Number of Pages:
11