| Abstract: | Since concentrations of trace elements in most natural waters seldom exceed the ??g/L level, analysis of trace elements in natural waters by inductively coupled plasma emission spectrometry (ICP) requires a preconcentration procedure. The elements Ag, Bi, Cd, Co, Cu, Fe, Mo, Ni, Pb, Sn, V, W, and Zn were separated and concentrated from 500 mL of water by coprecipitating them with sodium dibenzyldithiocarbamate (NaDBDTC) using nickel or silver as a carrier. The precipitated trace elements were collected on a membrane filter, redissolved from the filter with hot nitric and hydrochloric acids, and analyzed using ICP. Recoveries for all the trace elements except tungsten exceeded 80%. Coprecipitation of trace elements with NaDBDTC eliminated the use of difficult-to-inject organic solvents, and NaDBDTC coprecipitated a wider array of trace elements than ammoniumpyrrolidinedithiocarbamate (APDC), another commonly used coprecipitate. |
| Genre: | Article |
| ProdID: | 70012694 |
| Citation Author: | Smith, C. L.; Motooka, J. M.; Willson, W. R. |
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| Citation End Page: | 1730 |
| Citation Issue: | 15 A |
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| Citation Language: | English |
| Citation Larger Work Title: | Analytical Letters |
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| Citation Number Of Pages: | 16 |
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| Citation Search Results Text: | Analysis of trace metals in water by inductively coupled plasma emission spectrometry using sodium dibenzyldithiocarbamate for preconcentration; 1984; Article; Journal; Analytical Letters; Smith, C. L.; Motooka, J. M.; Willson, W. R. |
| Citation Start Page: | 1715 |
| Citation Volume: | 17 |
| Citation Year: | 1984 |
| Type: | citation/reference |
| Text: | Analysis of trace metals in water by inductively coupled plasma emission spectrometry using sodium dibenzyldithiocarbamate for preconcentration; 1984; Article; Journal; Analytical Letters; Smith, C. L.; Motooka, J. M.; Willson, W. R. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| Date Other: | Sun, 1 Jan 1984 00:00 -0600 |
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