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Pressure-composition relations for coexisting gases and liquids and the critical points in the system NaCl-H2O at 450, 475, and 500??C

Geochimica et Cosmochimica Acta

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Abstract

Pressure-temperature-composition (P, T, x) relations for the co-existing vapor and liquid phases in the system NaCl-H2O were determined experimentally at 450, 475, and 500??C. Data for each isotherm include P-x relations near the critical point and extend to the three-phase assemblage vapor-liquid-halite on the vapor side. On the liquid side the P-x data range from the critical point to the room-temperature halite saturation point (~25 wt.% NaCl). Critical pressures were calculated from measured pressures and compositions and classical theory. The results generally support the few data points of Urusova (1974, 1975) and O??lander and Liander (1950) but differ markedly from the extensive data of Sourirajan and Kennedy (1962). ?? 1987.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Pressure-composition relations for coexisting gases and liquids and the critical points in the system NaCl-H2O at 450, 475, and 500??C
Series title:
Geochimica et Cosmochimica Acta
Volume
51
Issue:
9
Year Published:
1987
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Geochimica et Cosmochimica Acta
First page:
2349
Last page:
2354