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Products of hexachlorocyclopentadiene (C-56) in aqueous solution

Environmental Toxicology and Chemistry

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Abstract

The photodegradation and degradation products of hexachlorocyclopentadiene (C-56) in aqueous solutions were studied in the laboratory. In each case, the half-life of C-56 was less than 4 min when exposed to sunlight. At least eight degradation products were positively or tentatively identified: 2,3,4,4,5-Pentachloro-2-cyclopentenone, hexachloro-2-cyclopentenone and hexachloro-3-cyclopentenone were the primary photodegradation products, and pentachlorocis-2,4-pentadienoic acid, Z- and E-pentachlorobutadiene and tetrachlorobutyne were the secondary degradation products. Dissociation of the primary photolysis products may proceed through corresponding pentadienoic acids to form smaller molecular weight compounds such as pentachlorobutadiene isomers and tetrachlorobutyne. In addition, dimerization of 2,3,4,4,5-pentachloro-2-cyclopentenone to form higher molecular weight compounds such as hexachloroindenone may present a minor route of degradation. The results also indicate that C-56 is highly photoreactive and suggest a possible pathway for the compound's transformation in the environment when exposed to sunlight. ?? 1987.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Products of hexachlorocyclopentadiene (C-56) in aqueous solution
Series title:
Environmental Toxicology and Chemistry
Volume
6
Issue:
5
Year Published:
1987
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Environmental Toxicology and Chemistry
First page:
371
Last page:
376
Number of Pages:
6