| Abstract: | This paper extends a four-step derivation procedure, previously presented for cases of transport affected by surface reactions, to transport problems involving homogeneous reactions. Derivations for these classes of reactions are used to illustrate the manner in which mathematical differences between reaction classes are reflected in the mathematical derivation procedures required to identify kinetically influenced terms. Simulation results for a case of transport affected by a single solution phase complexation reaction and for a case of transport affected by a precipitation-dissolution reaction are used to demonstrate the nature of departures from equilibrium-controlled transport as well as the use of kinetically influenced terms in determining criteria for the applicability of the local equilibrium assumption. A final derivation for a multireaction problem demonstrates the application of the generalized procedure to a case of transport affected by reactions of several classes. -from Author |
| Genre: | Article |
| ProdID: | 70016168 |
| Citation Author: | Bahr, J. M. |
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| Citation End Page: | 34 |
| Citation Issue: | 1 |
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| Citation Language: | English |
| Citation Larger Work Title: | Water Resources Research |
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| Citation Number Of Pages: | 14 |
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| Citation Search Results Text: | Kinetically influenced terms for solute transport affected by heterogeneous and homogeneous classical reactions; 1990; Article; Journal; Water Resources Research; Bahr, J. M. |
| Citation Start Page: | 21 |
| Citation Volume: | 26 |
| Citation Year: | 1990 |
| Type: | citation/reference |
| Text: | Kinetically influenced terms for solute transport affected by heterogeneous and homogeneous classical reactions; 1990; Article; Journal; Water Resources Research; Bahr, J. M. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| URL (DIGITAL OBJECT IDENTIFIER): | http://dx.doi.org/10.1029/89WR01545 |
| Date Other: | Mon, 1 Jan 1990 00:00 -0600 |
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