An experimental study of zinc chloride speciation from 300 to 600 °C and 0.5 to 2.0 kbar in buffered hydrothermal solutions
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Abstract
The solubility of sphalerite (ZnS) was measured in KCl-HCl-H2O solutions at 300–600°C and 0.5–2.0 kbar. The silicate assemblage K-feldspar-muscovite (or andalusite)-quartz was used to buffer the solution to acid conditions, resulting in the total solubility reaction 2K+ + KAl2AlSi3O10(OH)2 + 6SiO2 + ZnS + nCl− = ZnCln(2−n) + 3KAlSi3O8 + H2S. (muscovite) (quartz) (sphalerite) (K-feldspar) A computer retrieval technique was used to derive average chloride ligand numbers for chlorozinc species at 0.25–2.0 molal total chloride. This technique mathematically solves for the average ligand number using a series of pertinent chemical relations at P and T. Mono- and di-chlorozinc species were found to predominate throughout the pressure-temperature-composition range investigated. The logarithms of the first and second dissociation constants for ZnCl20 were evaluated over the P-T range; for example, at 1 kbar, the values −0.41 and −1.42 were computed for the logarithm of the first dissociation constant, while −7.62 and −10.57 were computed for the logarithm of the second dissociation constant, for 400 and 500°C, respectively. Results are compared to past studies conducted at subcritical conditions and differ in that we find no evidence for more highly coordinated chloro-zinc species except possibly for ZnCl3− at 600°C, 1 and 2 kbar. Our results are consistent with electrostatic theory, which favors lower charged to neutral molecules in low dielectric-constant media.
Publication type | Article |
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Publication Subtype | Journal Article |
Title | An experimental study of zinc chloride speciation from 300 to 600 °C and 0.5 to 2.0 kbar in buffered hydrothermal solutions |
Series title | Geochimica et Cosmochimica Acta |
DOI | 10.1016/0016-7037(94)90215-1 |
Volume | 58 |
Issue | 22 |
Year Published | 1994 |
Language | English |
Publisher | Elsevier |
Description | 15 p. |
First page | 4841 |
Last page | 4855 |
Online Only (Y/N) | N |
Additional Online Files (Y/N) | N |
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