| Abstract: | Additional studies on an incompletely characterized secondary uranium "mineral" from the Ruggles and Palermo granitic pegmatites, New Hampshire, referred to as mineral "A" by Frondel (1956), reveal a mixture of schoepite-group minerals and related uranyl oxide-hydroxide hydrated compounds. A composite chemical analysis yielded (in wt.%): PbO 4.85 (EMP), UO3 83.5 (EMP), BaO 0.675 (av. of EMP and ICP), CaO 0.167 (av. of EMP and ICP), K2O 2.455 (av. of EMP and ICP), SrO 0.21 (ICP), ThO2 0.85 (ICP), H2O 6.9, ??99.61. Powder-diffraction X-ray studies indicate a close resemblance in patterns between mineral "A" and several uranyl oxide-hydroxide hydrated minerals, including the schoepite family of minerals and UO2(OH)2. The powder-diffraction data for mineral "A" are most similar to those for synthetic UO2.86??1.5H2O and UO2(OH)2, but other phases are likely present as well. TGA analysis of both mineral "A" and metaschoepite show similar weight-loss and first derivative curves. The dominant losses are at 100??C, with secondary events at 400?? and 600??C. IR spectra show the presence of (OH) and H2O. Uraninite from both pegmatites, analyzed by LAM-ICP-MS, shows the presence of Th, Pb, K and Ca. |
| Genre: | Article |
| ProdID: | 70020133 |
| Citation Author: | Foord, E. E.; Korzeb, S. L.; Lichte, F. E.; Fitzpatrick, J. J. |
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| Citation End Page: | 151 |
| Citation Issue: | 1 |
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| Citation Language: | English |
| Citation Larger Work Title: | Canadian Mineralogist |
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| Citation Number Of Pages: | 7 |
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| Citation Search Results Text: | Additional studies on mixed uranyl oxide-hydroxide hydrate alteration products of uraninite from the palermo and ruggles granitic pegmatites, grafton county, New Hampshire; 1997; Article; Journal; Canadian Mineralogist; Foord, E. E.; Korzeb, S. L.; Lichte, F. E.; Fitzpatrick, J. J. |
| Citation Start Page: | 145 |
| Citation Volume: | 35 |
| Citation Year: | 1997 |
| Type: | citation/reference |
| Text: | Additional studies on mixed uranyl oxide-hydroxide hydrate alteration products of uraninite from the palermo and ruggles granitic pegmatites, grafton county, New Hampshire; 1997; Article; Journal; Canadian Mineralogist; Foord, E. E.; Korzeb, S. L.; Lichte, F. E.; Fitzpatrick, J. J. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| Date Other: | Wed, 1 Jan 1997 00:00 -0600 |
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