| Abstract: | Degradation products of the 2,3,6-/3,4,5-trimethyl substituted analog of isorenieratene were characterized in Belarussian petroleums. Devonian oils of low maturity were found to contain high concentrations (e.g., 35 mg/g) of C40 diaryl isoprenoids (2,3,6-/3,4,5-trimethyl substitution) along with an abundance of maturation-related compounds. A maturation scheme for diaryl carotenoid (2,3,6-/3,4,5-trimethyl substitution) precursors was proposed. Diaryl isoprenoids and aryl isoprenoid (2,3,6- and 3,4,5-trimethyl substitutions) contents were found to decrease as a function of maturity. Maturity parameters based on (i) the ratio of two specific C15 aryl isoprenoids and (ii) the ratio of C15 (2,3,6) aryl isoprenoids to C40 diaryl isoprenoids (2,3,6-/3,4,5) were proposed.Degradation products of the 2,3,6-/3,4,5-trimethyl substituted analog of isorenieratene were characterized in Belarussian petroleums. Devonian oils of low maturity were found to contain high concentrations (e.g., 35 mg/g) of C40 diaryl isoprenoids (2,3,6-/3,4,5-trimethyl substitution) along with an abundance of maturation-related compounds. A maturation scheme for diaryl carotenoid (2,3,6-/3,4,5-trimethyl substitution) precursors was proposed. Diaryl isoprenoids and aryl isoprenoid (2,3,6- and 3,4,5-trimethyl substitutions) contents were found to decrease as a function of maturity. Maturity parameters based on (i) the ratio of two specific C15 aryl isoprenoids and (ii) the ratio of C15 (2,3,6) aryl isoprenoids to C40 diaryl isoprenoids (2,3,6-/3,4,5) were proposed. |
| Genre: | Conference Paper |
| ProdID: | 70020483 |
| Citation Author: | Clifford, D. J.; Clayton, J. L.; Sinninghe, Damste, J. S. |
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| Citation End Page: | 1267 |
| Citation Issue: | 5-7 -7 pt 2 |
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| Citation Language: | English |
| Citation Larger Work Title: | Organic Geochemistry |
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| Citation Number Of Pages: | 15 |
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| Citation Publisher: | Elsevier Sci Ltd |
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| Citation Search Results Text: | 2,3,6-/3,4,5-Trimethyl substituted diaryl carotenoid derivatives (Chlorobiaceae) in petroleums of the Belarussian Pripyat River Basin; 1998; Conference Paper; Organic Geochemistry; Clifford, D. J.; Clayton, J. L.; Sinninghe, Damste, J. S. |
| Citation Start Page: | 1253 |
| Citation Volume: | 29 |
| Citation Year: | 1998 |
| Type: | citation/reference |
| Text: | 2,3,6-/3,4,5-Trimethyl substituted diaryl carotenoid derivatives (Chlorobiaceae) in petroleums of the Belarussian Pripyat River Basin; 1998; Conference Paper; Organic Geochemistry; Clifford, D. J.; Clayton, J. L.; Sinninghe, Damste, J. S. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| URL (DIGITAL OBJECT IDENTIFIER): | http://dx.doi.org/10.1016/S0146-6380(98)00086-2 |
| Date Other: | Thu, 1 Jan 1998 00:00 -0600 |
| Publisher: | Elsevier Sci Ltd |