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Re-evaluation and extension of the scope of elements in US Geological Survey Standard Reference Water Samples

Analyst

By:
, , , ,
DOI: 10.1039/a706350d

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Abstract

More than 100 US Geological Survey (USGS) Standard Reference Water Samples (SRWSs) were analyzed for numerous trace constituents, including Al, As, B, Ba, Be, Bi, Br, Cd, Cr, Co, Cu, I, Fe, Pb, Li, Mn, Mo, Ni, Rb, Sb, Se, Sr, Te, Tl, U, V, Zn and major elements (Ca, Mg, Na, SiO2, SO4, Cl) by inductively coupled plasma mass spectrometry and inductively coupled plasma atomic emission spectrometry. In addition, 15 USGS SRWSs and National Institute of Standards and Technology (NIST) standard reference material (SRM) 1641b were analyzed for mercury using cold vapor atomic fluorescence spectrometry. Also USGS SRWS Hg-7 was analyzed using isotope dilution-inductively coupled plasma mass spectrometry. The results were compared with the reported certified values of the following standard reference materials: NIST SRM 1643a, 1643b, 1643c and 1643d and National Research Council of Canada Riverine Water Reference Materials for Trace Metals SLRS-1, SLRS-2 and SLRS-3. New concentration values for trace and major elements in the SRWSs, traceable to the certified standards, are reported. Additional concentration values are reported for elements that were neither previously published for the SRWSs nor traceable to the certified reference materials. Robust statistical procedures were used that were insensitive to outliers. These data can be used for quality assurance/quality control purposes in analytical laboratories.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Re-evaluation and extension of the scope of elements in US Geological Survey Standard Reference Water Samples
Series title:
Analyst
DOI:
10.1039/a706350d
Volume
123
Issue:
3
Year Published:
1998
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
First page:
455
Last page:
476
Number of Pages:
22