Synthesis of new oligothiophene derivatives and their intercalation compounds: Orientation effects
Synthetic Metals
By: M.A. Ibrahim, B.-G. Lee, N.-G. Park, J.R. Pugh, D. D. Eberl, and A.J. Frank
Links
- More information: Publisher Index Page (via DOI)
- Download citation as: RIS | Dublin Core
Abstract
The orientation dependence of intercalated oligothiophene derivatives in vermiculite and metal disulfides MS2 (M = Mo, Ti and Zr) on the pendant group on the thiophene ring and the host material was studied by X-ray diffraction (XRD) and solid state nuclear magnetic resonance spectroscopy. Amino and nitro derivatives of bi-, ter- and quarter-thiophenes were synthesized for the first time. The amino-oligothiophenes were intercalated into vermiculite by an exchange reaction with previously intercalated octadecylammonium vermiculite and into MS2 by the intercalation-exfoliation technique. Analysis of the XRD data indicates that a monolayer of amino-oligothiophene orients perpendicularly to the silicate surface in vermiculite and lies flat in the van der Waals gap of MS2.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Synthesis of new oligothiophene derivatives and their intercalation compounds: Orientation effects |
| Series title | Synthetic Metals |
| DOI | 10.1016/S0379-6779(99)00037-5 |
| Volume | 105 |
| Issue | 1 |
| Year Published | 1999 |
| Language | English |
| Publisher | Elsevier Sequoia SA |
| Publisher location | Lausanne, Switzerland |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Synthetic Metals |
| First page | 35 |
| Last page | 42 |
| Google Analytic Metrics | Metrics page |