| Abstract: | Two ortho- (2,2‘,5 and 2,2‘,5,6‘) and a non-ortho- (3,3‘,4,4‘) substituted polychlorinated biphenyl (PCB) congeners were used to study the effects of sorbate structure in binding processes to two lacustrine fulvic acids. Binding constants were determined by solubility enhancement of the solutes by the fulvic acids. The binding of the ortho-trichlorobiphenyl was significantly less than the non-ortho-substituted tetrachlorobiphenyl to both fulvic acids. Surprisingly, the measured ortho-trichlorobiphenyl binding constant to both fulvic acids was approximately the same as the ortho- substituted tetrachlorobiphenyl. The effect of the chlorines in the ortho position inhibits free rotation around the 1,1‘ carbon bond, thereby making the molecule less able to interact effectively with the fulvic acid substrate relative to its non-ortho-substituted congeners. Finally, binding of all three PCBs to the Great Dismal Swamp fulvic acid was significantly higher than for the Pony Lake sample. This observation is attributable to the former substrate‘s higher degree of aromaticity and polarizability, which can potentially interact more favorably with the PCBs through an increase in van der Waals type interactions.Two ortho- (2,2???,5 and 2,2???,5,6???) and a non-ortho- (3,3???,4,4???) substituted polychlorinated biphenyl (PCB) congeners were used to study the effects of sorbate structure in binding processes to two lacustrine fulvic acids. Binding constants were determined by solubility enhancement of the solutes by the fulvic acids. The binding of the ortho-trichlorobiphenyl was significantly less than the non-ortho-substituted tetrachlorobiphenyl to both fulvic acids. Surprisingly, the measured ortho-trichlorobiphenyl binding constant to both fulvic acids was approximately the same as the ortho-substituted tetrachlorobiphenyl. The effect of the chlorines in the ortho position inhibits free rotation around the 1,1??? carbon bond, thereby making the molecule less able to interact effectively with the fulvic acid substrate relative to its non-ortho-substituted congeners. Finally, binding of all three PCBs to the Great Dismal Swamp fulvic acid was significantly higher than for the Pony Lake sample. This observation is attributable to the former substrate‘s higher degree of aromaticity and polarizability, which can potentially interact more favorably with the PCBs through an increase in van der Waals type interactions. |
| Genre: | Article |
| ProdID: | 70021856 |
| Citation Author: | Uhle, M. E.; Chin, Y. -P.; Aiken, G. R.; McKnight, D. M. |
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| Citation End Page: | 2718 |
| Citation Issue: | 16 |
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| Citation Language: | English |
| Citation Larger Work Title: | Environmental Science and Technology |
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| Citation Number Of Pages: | 4 |
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| Citation Publisher: | ACS |
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| Citation Search Results Text: | Binding of polychlorinated biphenyls to aquatic humic substances: The role of substrate and sorbate properties on partitioning; 1999; Article; Journal; Environmental Science and Technology; Uhle, M. E.; Chin, Y. -P.; Aiken, G. R.; McKnight, D. M. |
| Citation Start Page: | 2715 |
| Citation Volume: | 33 |
| Citation Year: | 1999 |
| Type: | citation/reference |
| Text: | Binding of polychlorinated biphenyls to aquatic humic substances: The role of substrate and sorbate properties on partitioning; 1999; Article; Journal; Environmental Science and Technology; Uhle, M. E.; Chin, Y. -P.; Aiken, G. R.; McKnight, D. M. |
| URL (THUMBNAIL): | http://pubs.er.usgs.gov/thumbnails/outside_thumb.jpg |
| URL (DIGITAL OBJECT IDENTIFIER): | http://dx.doi.org/10.1021/es9808447 |
| Date Other: | Fri, 1 Jan 1999 00:00 -0600 |
| Publisher: | ACS |
