From 1994 through 1998, the eruption of Kîlauea, in Hawai’i, was dominated by steady-state effusion at Pu‘u ‘Ô‘ô that was briefly disrupted by an eruption 4 km uprift at Nāpau Crater on January 30, 1997. In this paper, I describe the systematic relations of whole-rock, glass, olivine, and olivine-inclusion compositions of lava samples collected throughout this interval. This suite comprises vent samples and tube-contained flows collected at variable distances from the vent. The glass composition of tube lava varies systematically with distance and allows for the “vent-correction” of glass thermometry and olivine–liquid K_D as a function of tube-transport distance. Combined olivine–liquid data for vent samples and “vent-corrected” lava-tube samples are used to document pre-eruptive magmatic conditions. K_D values determined for matrix glasses and forsterite cores define three types of olivine phenocrysts: type A (in equilibrium with host glass), type B (Mg-rich relative to host glass) and type C (Mg-poor relative to host glass). All three types of olivine have a cognate association with melts that are present within the shallow magmatic plumbing system during this interval. During steady-state eruptive activity, the compositions of whole-rock, glass and most olivine phenocrysts (type A) all vary sympathetically over time and as influenced by changes of magmatic pressure within the summit-rift-zone plumbing system. Type-A olivine is interpreted as having grown during passage from the summit magma-chamber along the east-rift-zone conduit. Type-B olivine (high Fo) is consistent with equilibrium crystallization from bulk-rock compositions and is likely to have grown within the summit magma-chamber. Lower-temperature, fractionated lava was erupted during non-steady-state activity of the Nāpau Crater eruption. Type-A and type-B olivine–liquid relations indicate that this lava is a mixture of rift-stored and summit-derived magmas. Post- Nāpau lava (at Pu‘u ‘Ô‘ô) gradually increases in temperature and MgO content, and contains type-C olivine with complex zoning, indicating magma hybridization associated with the flushing of rift-stored components through the eruption conduit.