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Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions

Journal of Chemical Physics

By:
, , , , and
DOI: 10.1063/1.1524616

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Abstract

Recently x-ray absorption fine structure (XAFS) studies of various ions in aqueous solutions showed a variation of cation-ligand bond lengths, often coupled with other structure changes, with increasing temperatures. Thus, the variations of the structure of several metal ion complexes with temperature based on observations from the X-ray absorption fine structure (XAFS) studies in the hope that it will stimulate the development of either first- principles theory or molecular dynamics simulations that might adequately describes these results are discussed.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions
Series title:
Journal of Chemical Physics
DOI:
10.1063/1.1524616
Volume
118
Issue:
2
Year Published:
2003
Language:
English
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
Larger Work Title:
Journal of Chemical Physics
First page:
719
Last page:
727