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Point sources of emerging contaminants along the Colorado River Basin: Source water for the arid Southwestern United States

Science of the Total Environment

By:
, , , ,
DOI: 10.1016/j.scitotenv.2012.04.053

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Abstract

Emergingcontaminants (ECs) (e.g., pharmaceuticals, illicit drugs, personal care products) have been detected in waters across the UnitedStates. The objective of this study was to evaluate pointsources of ECs along the ColoradoRiver, from the headwaters in Colorado to the Gulf of California. At selected locations in the ColoradoRiver Basin (sites in Colorado, Utah, Nevada, Arizona, and California), waste stream tributaries and receiving surface waters were sampled using either grab sampling or polar organic chemical integrative samplers (POCIS). The grab samples were extracted using solid-phase cartridge extraction (SPE), and the POCIS sorbents were transferred into empty SPEs and eluted with methanol. All extracts were prepared for, and analyzed by, liquid chromatography-electrospray-ion trap mass spectrometry (LC-ESI-ITMS). Log Dow values were calculated for all ECs in the study and compared to the empirical data collected. POCIS extracts were screened for the presence of estrogenic chemicals using the yeast estrogen screen (YES) assay. Extracts from the 2008 POCIS deployment in the Las Vegas Wash showed the second highest estrogenicity response. In the grab samples, azithromycin (an antibiotic) was detected in all but one urban waste stream, with concentrations ranging from 30 ng/L to 2800 ng/L. Concentration levels of azithromycin, methamphetamine and pseudoephedrine showed temporal variation from the Tucson WWTP. Those ECs that were detected in the main surface water channels (those that are diverted for urban use and irrigation along the ColoradoRiver) were in the region of the limit-of-detection (e.g., 10 ng/L), but most were below detection limits.

Additional Publication Details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Point sources of emerging contaminants along the Colorado River Basin: Source water for the arid Southwestern United States
Series title:
Science of the Total Environment
DOI:
10.1016/j.scitotenv.2012.04.053
Volume
430
Year Published:
2012
Language:
English
Publisher:
Elsevier
Publisher location:
Amsterdam, Netherlands
Contributing office(s):
Columbia Environmental Research Center
Description:
9 p.
Larger Work Type:
Article
Larger Work Subtype:
Journal Article
First page:
237
Last page:
245
Country:
United States
State:
Arizona;California;Colorado;Nevada;New Mexico;Utah