Chromium isotopes and the fate of hexavalent chromium in the environment

Science
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Abstract

Measurements of chromium (Cr) stable-isotope fractionation in laboratory experiments and natural waters show that lighter isotopes reacted preferentially during Cr(VI) reduction by magnetite and sediments. The 53Cr/52Cr ratio of the product was 3.4 ± 0.1 per mil less than that of the reactant.53Cr/52Cr shifts in water samples indicate the extent of reduction, a critical process that renders toxic Cr(VI) in the environment immobile and less toxic.

Publication type Article
Publication Subtype Journal Article
Title Chromium isotopes and the fate of hexavalent chromium in the environment
Series title Science
DOI 10.1126/science.1068368
Volume 295
Issue 5562
Year Published 2002
Language English
Publisher American Association for the Advancement of Science
Contributing office(s) Toxic Substances Hydrology Program
Description 3 p.
First page 2060
Last page 2062
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