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A fluorimetric study of the thorium-morin system

Trace Elements Investigations 589

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and

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Abstract

Thorium reacts with morin to yield a yellow complex that fluoresces when irradiated with ultraviolet light. The effect on the fluorescence of such variable as concentration of acid, alcohol, thorium, morin, and complex; time, temperature, and wavelength of exciting light are studied to determine experimental conditions yielding maximum fluorescence. The effects of Zr4+, Al3+, Fe3+, Ca2+, and La3+ are discussed.


The fundamental relationships between light absorption and fluorescence are expressed in a general equation which applied to a three-component system when the fluorescence is measured in a transmission-type fluorimeter. This general equation is used to obtain an expression for the fluorescence of the thorium-morin system.


Equations, derived from experimental data, related both the fraction of thorium reacted to form complex and the fraction of unquenched fluorescence to the concentration of uncombined morin. These functions, when combined with the general equation, give an expression which relates the total net fluorescence to the amount of uncombined morin in the solution. This last equation can be used to determine the one region for the concentration of uncombined morin that gives maximum sensitivity for the system. Calculated standard curves are in excellent agreement with experimental curves.

Additional Publication Details

Publication type:
Report
Publication Subtype:
USGS Numbered Series
Title:
A fluorimetric study of the thorium-morin system
Series title:
Trace Elements Investigations
Series number:
589
Year Published:
1956
Language:
English
Publisher:
U.S. Geological Survey
Description:
56 p.
Number of Pages:
57