Determination of the δ<sup>34</sup>S of low-concentration sulfate in water; RSIL lab code 1949

Revesz, Kinga; Qi, Haiping; Coplen, Tyler B.

Abstract:

The purpose of the Reston Stable Isotope Laboratory (RSIL) lab code 1949 is to determine the δ(³⁴S/³²S), abbreviated as δ³⁴S, of dissolved sulfate having a concentration less than 20 milligrams per liter. Dissolved sulfate is collected on an anion-exchange resin in the field, eluted in the laboratory with 3 M KCl, and precipitated with BaCl₂ at pH 3 to 4 as BaSO₄. The precipitated BaSO₄ is filtered and dried before introduction into an elemental analyzer (EA) Carlo Erba NC 2500. The EA is used to convert sulfur in a BaSO₄ solid sample into SO₂ gas, and the EA is connected to a continuous flow isotope-ratio mass spectrometer (CF-IRMS), which determines differences in the isotope-amount ratios of stable sulfur isotopes (³⁴S/³²S) of the product SO₂ gas. The combustion is quantitative; no isotopic fractionation is involved. Samples are placed in a tin capsule and loaded into the Costech Zero Blank Autosampler of the EA. Under computer control, samples are dropped into a heated reaction tube that combines the oxidation and reduction reactions. The combustion takes place in a helium atmosphere containing an excess of oxygen gas at the oxidation zone at the top of the reaction tube. Combustion products are transported by a helium carrier through the reduction zone at the bottom of the reaction tube to remove excess oxygen and through a separate drying tube to remove any water. The gas-phase products, mainly CO₂, N₂, and SO₂, are separated by a gas chromatograph. The gas is then introduced into the isotope-ratio mass spectrometer (IRMS) through a Finnigan MAT (now Thermo Scientific) ConFlo II interface, which is also used to inject SO₂ reference gas and helium for sample dilution. The IRMS is a Thermo Scientific Delta V Plus CF-IRMS. It has a universal triple collector with two wide cups and a narrow cup in the middle. It is capable of measuring mass/charge (m/z) 64 and 66 simultaneously. The ion beams from SO₂ are as follows: m/z 64 = SO₂ = ³²S¹⁶O¹⁶O; m/z 66 = SO₂ = ³⁴S¹⁶O¹⁶O primarily.

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USGS Numbered Series

ProdID:

76903

Citation Author:

Revesz, Kinga; Qi, Haiping; Coplen, Tyler B.

Citation Contributing Office:

Reston Stable Isotope Laboratory

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Version 1.0 - May 2006, Version 1.1 - 2007, Version 1.2 - September 2012

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English

Citation Larger Work Title:

Chapter 8 of Book 10, Methods of the Reston Stable Isotope Laboratory, Section C, Stable Isotope-Ratio Methods

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viii, 35 p.

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U.S. Geological Survey

Citation Series:

Techniques and Methods

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Citation Series Number:

10-C8

Citation Search Results Text:

Determination of the δ³⁴S of low-concentration sulfate in water; RSIL lab code 1949; 2006; TM; 10-C8; Chapter 8 of Book 10, Methods of the Reston Stable Isotope Laboratory, Section C, Stable Isotope-Ratio Methods; Revesz, Kinga; Qi, Haiping; Coplen, Tyler B.