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Chapter A6. Section 6.5. Reduction-Oxidation Potential (Electrode Method)

Techniques of Water-Resource Investigation 09-A6.5

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Abstract

Reduction-oxidation (redox) potential--also referred to as Eh--is a measure of the equilibrium potential, relative to the standard hydrogen electrode, developed at the interface between a noble metal electrode and an aqueous solution containing electroactive chemical species. Measurements of Eh are used to evaluate geochemical speciation models, and Eh data can provide insights on the evolution and status of water chemistry in an aqueous system. Nevertheless, the measurement is fraught with inherent interferences and limitations that must be understood and considered to determine applicability to the aqueous system being studied. For this reason, Eh determination is not one of the field parameters routinely measured by the U.S. Geological Survey (USGS). This section of the National Field Manual (NFM) describes the equipment and procedures needed to measure Eh in water using a platinum electrode. Guidance as to the limitations and interpretation of Eh measurement also is included.

Additional Publication Details

Publication type:
Report
Publication Subtype:
USGS Numbered Series
Title:
Chapter A6. Section 6.5. Reduction-Oxidation Potential (Electrode Method)
Series title:
Techniques of Water-Resource Investigation
Series number:
09-A6.5
Edition:
Version 1.2
Year Published:
2005
Language:
ENGLISH
Publisher:
Geological Survey (U.S.)
Contributing office(s):
U.S. Geological Survey
Description:
22 p.
Larger Work Type:
Report
Larger Work Subtype:
USGS Numbered Series
Larger Work Title:
National Field Manual for the Collection of Water-Quality Data. U.S. Geological Survey Techniques of Water-Resources Investigations, Book 9