Uranyl ion coordination
Science
By: H. T. Evans Jr.
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Abstract
A review of the known crystal structures containing the uranyl ion shows that plane-pentagon coordination is equally as prevalent as plane-square or plane-hexagon. It is suggested that puckered-hexagon configurations of OH - or H2O about the uranyl group will tend to revert to plane-pentagon coordination. The concept of pentagonal coordination is invoked for possible explanations of the complex crystallography of the natural uranyl hydroxides and the unusual behavior of polynuclear ions in hydrolyzed uranyl solutions.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Uranyl ion coordination |
| Series title | Science |
| Volume | 141 |
| Issue | 3576 |
| Year Published | 1963 |
| Language | English |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Science |
| First page | 154 |
| Last page | 158 |
| Google Analytic Metrics | Metrics page |