Conventional K-Ar ages of tholeiitic basalts of the Ferrar Group in the central Transantarctic Mountains indicate significant loss of radiogenic ⁴⁰Ar from this unit over much of its outcrop area. Argon loss varies inversely with amount of devitrified matrix in the basalts, which have not been thermally or tectonically disturbed since extrusion. ⁴⁰Ar/¹⁹Ar age-spectra of these tholeiites are generally discordant and indicate significant inhomogeneity in the distribution of radiogenic ⁴⁰Ar with respect to ³⁹Ar, but are distinctly different from release patterns of thermally disturbed samples. Amounts of argon redistribution vary directly with amounts of devitrification and are reflected in progressive modification of the age spectra. A model of redistribution of radiogenic ⁴⁰Ar by devitrification of originally glassy matrix is suggested that is consistent with disturbance of the conventional K-Ar systematics as well as the ⁴⁰Ar/³⁹Ar age-spectra. Samples with substantial redistribution but minor loss of radiogenic argon yield age spectra whose apparent ages decrease from low-temperature to high-temperature steps, similar to those reported for some lunar basalts, breccias, and soils. Modification of all the age spectra is attributed to redistribution of radiogenic ⁴⁰Ar during progressive devitrification, although ³⁹Ar-recoil effects suggested by Turner and Cadogan (1974) may be a factor in some cases. Where devitrification involves most potassium sites within the basalt, ⁴⁰Ar/³⁹Ar age-plateaux may be formed that have no geologic significance.