Laser induced fluorescence spectra of fluorophenol cations in a Ne matrix
Journal of Chemical Physics
By: V.E. Bondybey, J.H. English, T.A. Miller, and R.H. Shiley
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Abstract
Laser induced fluorescence and/or absorption spectra of the cations of 2,3,5,6‐tetrafluorophenol, 2,3,5,6‐tetrafluorothiophenol, and 3,5‐difluorophenol have been obtained in a Ne matrix. The spectra of C6HF4OH+ are much better resolved than in the gas phase. The gas phase congestion is likely caused by the near degeneracy of the and electronic states whose separation is now measured at 207 cm−1. The spectrum of C6H3F2OH+ represents a deperturbed example of the Jahn–Teller distorted sym‐C6F3H3+ ion. C6H3F2SH+ shows only a broad featureless absorption.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Laser induced fluorescence spectra of fluorophenol cations in a Ne matrix |
| Series title | Journal of Chemical Physics |
| DOI | 10.1063/1.445067 |
| Volume | 78 |
| Issue | 5 |
| Year Published | 1983 |
| Language | English |
| Publisher | American Institute of Physics |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Journal of Chemical Physics |
| First page | 2227 |
| Last page | 2230 |
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