Terpenoid marker compounds derived from biogenic precursors in volcanic ash from Mount St. Helens, Washington

Geochimica et Cosmochimica Acta
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Abstract

A volcanic-ash sample obtained after the 1980 eruption of Mount St. Helens, Washington, was analyzed for cyclic terpenoid organic compounds and polycyclic aromatic hydrocarbons using capillary gas chromatography-mass spectrometry-computer techniques. Various tricyclic diterpenoid acids and hydrocarbons were identified including dehydroabietic acid, dehydroabietin, dehydroabietane, simonellite, and retene. Preliminary evidence indicates that these compounds were derived from forest soils or atmospheric aerosols or both in the vicinity of coniferous forests. A diagenetic scheme involving three possible pathways for the conversion of abietic acid to retene is presented.

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Publication type Article
Publication Subtype Journal Article
Title Terpenoid marker compounds derived from biogenic precursors in volcanic ash from Mount St. Helens, Washington
Series title Geochimica et Cosmochimica Acta
DOI 10.1016/0016-7037(83)90052-2
Volume 47
Issue 12
Year Published 1983
Language English
Publisher Elsevier
Contributing office(s) Toxic Substances Hydrology Program
Description 5 p.
First page 2287
Last page 2291
Country United States
State Washington
Other Geospatial Mount St. Helens
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