Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase
Links
- More information: Publisher Index Page (via DOI)
- Download citation as: RIS | Dublin Core
Abstract
Emission spectra of the cations of 2,5- and 3,5-difluorophenol, of 2,3,4- and 2,4,5-trifluorophenol, of 2,3,5,6-tetrafluorophenol and of 2,3,4,5,6-pentafluorophenol have been obtained in the gas phase using low-energy electron beam excitation. The band systems are assigned to the B̃(π−1) → X̃(π−1) electronic transitions of these cations by reference to photoelectron spectroscopic data. The He(Iα) photoelectron spectra and the ionisation energies of ten fluoro-substituted phenols are reported. The symmetries of the four lowest electronic states of these cations are inferred from the radiative decay studies. The lifetimes of the lowest vibrational levels of the B̃(π−1) state of the six fluoro-substituted phenol cations above have also been measured.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase |
| Series title | Journal of Electron Spectroscopy and Related Phenomena |
| DOI | 10.1016/0368-2048(80)80031-4 |
| Volume | 19 |
| Issue | 1 |
| Year Published | 1980 |
| Language | English |
| Publisher | Elsevier |
| Description | 10 p. |
| First page | 11 |
| Last page | 20 |
| Google Analytic Metrics | Metrics page |