Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase
Journal of Electron Spectroscopy and Related Phenomena
By: John Paul Maier, O. Marthaler, Manijeh Mohraz, and R.H. Shiley
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Abstract
Emission spectra of the cations of 2,5- and 3,5-difluorophenol, of 2,3,4- and 2,4,5-trifluorophenol, of 2,3,5,6-tetrafluorophenol and of 2,3,4,5,6-pentafluorophenol have been obtained in the gas phase using low-energy electron beam excitation. The band systems are assigned to the B??(??-1) ??? X??(??-1) electronic transitions of these cations by reference to photoelectron spectroscopic data. The He(I??) photoelectron spectra and the ionisation energies of ten fluoro-substituted phenols are reported. The symmetries of the four lowest electronic states of these cations are inferred from the radiative decay studies. The lifetimes of the lowest vibrational levels of the B??(??-1) state of the six fluoro-substituted phenol cations above have also been measured. ?? 1980.
| Publication type | Article |
|---|---|
| Publication Subtype | Journal Article |
| Title | Emission spectra of the cations of some fluoro-substituted phenols in the gaseous phase |
| Series title | Journal of Electron Spectroscopy and Related Phenomena |
| Volume | 19 |
| Issue | 1 |
| Year Published | 1980 |
| Language | English |
| Larger Work Type | Article |
| Larger Work Subtype | Journal Article |
| Larger Work Title | Journal of Electron Spectroscopy and Related Phenomena |
| First page | 11 |
| Last page | 20 |
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