Spectral characteristics of chlorites and Mg‐serpentines using high‐resolution reflectance spectroscopy

Journal of Geophysical Research: Solid Earth
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Abstract

The present laboratory study using high‐resolution reflectance spectroscopy (0.25–2.7 μm) focuses on two primary phyllosilicate groups, serpentines and chlorites. The results show that it is possible to spectrally distinguish between isochemical end‐members of the Mg‐rich serpentine group (chrysotile, antigorite, and lizardite) and to recognize spectral variations in chlorites as a function of Fe/Mg ratio (∼8–38 wt % Fe). The position and relative strength of the 1.4‐μm absorption feature in the trioctahedral chlorites appear to be correlated to the total iron content and/or the Mg/Si ratio and the loss on ignition values of the sample. Spectral differences in the 2.3‐μm wavelength region can be attributed to differences in lattice environments and are characteristic for specific trioctahedral chlorites. The 1.4‐μm feature in the isochemical Mg‐rich serpentines (total iron content ∼1.5–7.0 wt%) show marked spectral differences, apparently due to structural differences.

Publication type Article
Publication Subtype Journal Article
Title Spectral characteristics of chlorites and Mg‐serpentines using high‐resolution reflectance spectroscopy
Series title Journal of Geophysical Research: Solid Earth
DOI 10.1029/JB094iB10p13997
Volume 94
Issue B10
Year Published 1989
Language English
Publisher American Geophysical Union
Contributing office(s) Crustal Geophysics and Geochemistry Science Center
Description 12 p.
First page 13997
Last page 14008
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