Volatile emissions from the crater and flank of Oldoinyo Lengai volcano, Tanzania

Journal of Geophysical Research B: Solid Earth
By: , and 



As a comparison to airborne infrared (IR) flux measurements, ground-based sampling of fumarole and soil gases was used to characterize the quiescent degassing of CO2 from Oldoinyo Lengai volcano. Aerial and ground-based measurements are in good agreement: ~75% of the aerially measured CO2 flux at Lengai (0.05-0.06 x 1012 mol yr-1 or 6000-7200 tonnes CO2 d-1) can be attributed to seven large crater vents. In contrast to Etna and Vulcano Island, where 15-50% of the total CO2 flux emanates diffusely through the volcanic flanks, diffuse emissions were measured only within 500 m of the crater rim at Lengai, contributing < 2% of the total flux. The lack of extensive flank emissions may reflect the dimensions of the magma chamber and/or the lack of a shallow fluid flow system. Thermodynamic restoration of fumarole analyses shows that gases are the most CO2-rich and H2O-poor reported for any volcano, containing 64-74% CO2, 24-34% H2O, 0.88-1.0% H2, 0.1-0.4% CO and < 0.1% H2S, HCl, HF, and CH4. Volatile emissions of S, Cl, and F at Oldoiyno Lengai are estimated as 4.5, 1.5, and 1.0 x 107 mol yr-1, respectively. Accuracy of the airborne technique was also assessed by measuring the C emission rate from a coal-burning power plant. CO2 fluxes were measured within +/-10% near the plant; however, poor resolution at increased distances caused an underestimation of the flux by a factor of 2. The relatively large CO2 fluxes measured for alkaline volcanoes such as Oldoinyo Lengai or Etna may indicate that midplate volcanoes represent a large, yet relatively unknown, natural source of CO2.

Additional publication details

Publication type Article
Publication Subtype Journal Article
Title Volatile emissions from the crater and flank of Oldoinyo Lengai volcano, Tanzania
Series title Journal of Geophysical Research B: Solid Earth
Volume 101
Issue 6
Year Published 1996
Language English
Publisher AGU
Contributing office(s) Volcano Hazards Program
Description 12 p.
First page 13819
Last page 13830
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