Geologic mapping, together with 73 new K-Ar and ⁴⁰Ar/³⁹Ar age determinations of 45 samples from 17 different volcanic units, plus paleomagnetic orientations, geochemical compositions, and terrestrial photogrammetry are used to define the chronostratigraphy of the Tatara–San Pedro complex, an eruptive center at 36°S on the volcanic front of the Andean southern volcanic zone. The Tatara–San Pedro complex preserves ≈55 km³ of lavas that erupted from at least three central vent regions. Remnant, unconformity-bound sequences of lavas are separated by lacunae that include significant periods of erosion. Quaternary volcanism commenced ca. 930 ka with eruption of voluminous dacitic magma, followed 100 k.y. later by the only major rhyolitic eruption. From 780 ka onward, more than 80% of the preserved volume is basaltic andesite (52%–57% SiO₂), but petrographically and geochemically diverse dacitic magmas (63%–69% SiO₂) erupted sporadically throughout this younger, dominantly mafic phase of activity. A few basaltic lavas (49%–52% SiO₂) are present, mainly in portions of the complex older than 230 ka. The number of vents, the petrologic and geochemical diversity, and the temporal distribution of mafic and silicic lavas are consistent with emplacement of many separate batches of mafic magma into the shallow crust beneath the Tatara–San Pedro complex over the past million years.