Transport and fate of nitrate in a glacial outwash aquifer in relation to ground water age, land use practices, and redox processes

Journal of Environmental Quality
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Abstract

A combination of ground water modeling, chemical and dissolved gas analyses, and chlorofluorocarbon age dating of water was used to determine the relation between changes in agricultural practices, and NO3 concentrations in ground water of a glacial outwash aquifer in west-central Minnesota. The results revealed a redox zonation throughout the saturated zone with oxygen reduction occurring near the water table, NO3 reduction immediately below it, and then a large zone of ferric iron reduction, with a small area of sulfate (SO2−4) reduction and methanogenesis (CH4) near the end of the transect. Analytical and NETPATH modeling results supported the hypothesis that organic carbon served as the electron donor for the redox reactions. Denitrification rates were quite small, 0.005 to 0.047 mmol NO3 yr−1, and were limited by the small amounts of organic carbon, 0.01 to 1.45%. In spite of the organic carbon limitation, denitrification was virtually complete because residence time is sufficient to allow even slow processes to reach completion. Ground water sample ages showed that maximum residence times were on the order of 50 to 70 yr. Reconstructed NO3 concentrations, estimated from measured NO3 and dissolved N gas showed that NO3 concentrations have been increasing in the aquifer since the 1940s, and have been above the 714 μmol L−1 maximum contaminant level at most sites since the mid- to late-1960s. This increase in NO3 has been accompanied by a corresponding increase in agricultural use of fertilizer, identified as the major source of NO3 to the aquifer.

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Publication type Article
Publication Subtype Journal Article
Title Transport and fate of nitrate in a glacial outwash aquifer in relation to ground water age, land use practices, and redox processes
Series title Journal of Environmental Quality
DOI 10.2134/jeq2002.7820
Volume 31
Issue 3
Year Published 2002
Language English
Publisher American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America
Contributing office(s) National Water Quality Assessment Program
Description 15 p.
First page 782
Last page 796
Country United States
State Minnesota
Other Geospatial Big Pine Lake, Little Pine Lake, Otter Tail River
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