Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions

Journal of Chemical Physics
By: , and 

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Abstract

Recently x-ray absorption fine structure (XAFS) studies of various ions in aqueous solutions showed a variation of cation-ligand bond lengths, often coupled with other structure changes, with increasing temperatures. Thus, the variations of the structure of several metal ion complexes with temperature based on observations from the X-ray absorption fine structure (XAFS) studies in the hope that it will stimulate the development of either first- principles theory or molecular dynamics simulations that might adequately describes these results are discussed.

Additional publication details

Publication type Article
Publication Subtype Journal Article
Title Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions
Series title Journal of Chemical Physics
DOI 10.1063/1.1524616
Volume 118
Issue 2
Year Published 2003
Language English
Larger Work Type Article
Larger Work Subtype Journal Article
Larger Work Title Journal of Chemical Physics
First page 719
Last page 727