Quantifying watershed-scale groundwater loading and in-stream fate of nitrate using high-frequency water quality data

Water Resources Research
By: , and 



We describe a new approach that couples hydrograph separation with high-frequency nitrate data to quantify time-variable groundwater and runoff loading of nitrate to streams, and the net in-stream fate of nitrate at the watershed-scale. The approach was applied at three sites spanning gradients in watershed size and land use in the Chesapeake Bay watershed. Results indicate that 58-73% of the annual nitrate load to the streams was groundwater-discharged nitrate. Average annual first order nitrate loss rate constants (k) were similar to those reported in both modelling and in-stream process-based studies, and were greater at the small streams (0.06 and 0.22 d-1) than at the large river (0.05 d-1), but 11% of the annual loads were retained/lost in the small streams, compared with 23% in the large river. Larger streambed area to water volume ratios in small streams result in greater loss rates, but shorter residence times in small streams result in a smaller fraction of nitrate loads being removed than in larger streams. A seasonal evaluation of k values suggests that nitrate was retained/lost at varying rates during the growing season. Consistent with previous studies, streamflow and nitrate concentration were inversely related to k. This new approach for interpreting high-frequency nitrate data and the associated findings furthers our ability to understand, predict, and mitigate nitrate impacts on streams and receiving waters by providing insights into temporal nitrate dynamics that would be difficult to obtain using traditional field-based studies.

Study Area

Publication type Article
Publication Subtype Journal Article
Title Quantifying watershed-scale groundwater loading and in-stream fate of nitrate using high-frequency water quality data
Series title Water Resources Research
DOI 10.1002/2015WR017753
Volume 52
Issue 1
Year Published 2016
Language English
Publisher American Geophysical Union
Publisher location Washington, D.C.
Contributing office(s) California Water Science Center, Minnesota Water Science Center, New York Water Science Center, Oregon Water Science Center, Utah Water Science Center, Virginia Water Science Center
Description 18 p.
First page 330
Last page 347
Country United States
State Delaware, Pennsylvania, Maryland, New York, Virginia, West Virginia
Other Geospatial Chesapeake Bay watershed
Online Only (Y/N) N
Additional Online Files (Y/N) N
Google Analytic Metrics Metrics page
Additional publication details