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Tree sampling as a method to assess vapor intrusion potential at a site characterized by VOC-contaminated groundwater and soil

Environmental Science & Technology

By:
, , , , and
https://doi.org/10.1021/acs.est.7b02667

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Abstract

Vapor intrusion (VI) by volatile organic compounds (VOCs) in the built environment presents a threat to human health. Traditional VI assessments are often time-, cost-, and labor-intensive; whereas traditional subsurface methods sample a relatively small volume in the subsurface and are difficult to collect within and near structures. Trees could provide a similar subsurface sample where roots act as the “sampler’ and are already onsite. Regression models were developed to assess the relation between PCE concentrations in over 500 tree-core samples with PCE concentrations in over 50 groundwater and 1000 soil samples collected from a tetrachloroethylene- (PCE-) contaminated Superfund site and analyzed using gas chromatography. Results indicate that in planta concentrations are significantly and positively related to PCE concentrations in groundwater samples collected at depths less than 20 m (adjusted R2 values greater than 0.80) and in soil samples (adjusted R2 values greater than 0.90). Results indicate that a 30 cm diameter tree characterizes soil concentrations at depths less than 6 m over an area of 700–1600 m2, the volume of a typical basement. These findings indicate that tree sampling may be an appropriate method to detect contamination at shallow depths at sites with VI.

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Additional publication details

Publication type:
Article
Publication Subtype:
Journal Article
Title:
Tree sampling as a method to assess vapor intrusion potential at a site characterized by VOC-contaminated groundwater and soil
Series title:
Environmental Science & Technology
DOI:
10.1021/acs.est.7b02667
Volume:
51
Issue:
18
Year Published:
2017
Language:
English
Publisher:
ACS Publications
Contributing office(s):
Missouri Water Science Center
Description:
10 p.
First page:
10369
Last page:
10378
Country:
United States
State:
Missouri
City:
Vienna