Spatial and temporal variation in sources of atmospheric nitrogen deposition in the Rocky Mountains using nitrogen isotopes

Atmospheric Environment
By: , and 

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Abstract

Variation in source areas and source types of atmospheric nitrogen (N) deposition to high-elevation ecosystems in the Rocky Mountains were evaluated using spatially and temporally distributed N isotope data from atmospheric deposition networks for 1995-2016. This unique dataset links N in wet deposition and snowpack to mobile and stationary emissions sources, and enhances understanding of the impacts of anthropogenic activities and environmental policies that mitigate effects of accelerated N cycling across the Rocky Mountain region. δ15N−NO3 at 50 U.S. Geological Survey Rocky Mountain Snowpack (Snowpack) sites ranged from −3.3‰ to +6.5‰, with a mean value of +1.4‰. At 15 National Atmospheric Deposition Program (NADP)/National Trends Network wet deposition (NADP Wetfall) sites, summer δ15N−NO3 is significantly lower ranging from −7.6‰ to −1.3‰ while winter δ15N−NO3 ranges from −2.6‰ to +5.5‰, with a mean value of +0.7‰ during the cool season. The strong seasonal difference in NADP Wetfall δ15N−NO3 is due in part to variation in the proportion of N originating from source regions at different times of the year due to seasonal changes in weather patterns. Snowpack NO3 and δ15N−NO3 are significantly related to NADP Wetfall (fall and winter) suggesting that bulk snowpack samples provide a reliable estimate at high elevations. Spatial trends show higher NO3concentrations and δ15N−NO3 in the Southern Rocky Mountains located near larger anthropogenic N emission sources compared to the Northern Rocky Mountains. NADP Wetfall δ15N−NH4+ ranged from −10‰ to 0‰, with no observed spatial pattern. However, the lowest δ15N−NH4+(−9‰), and the highest NH4+ concentration (35 μeq/L) were observed at a Utah site dominated by local agricultural activities, whereas the higher δ15N−NH4+observed in Colorado and Wyoming are likely due to mixed sources, including fossil fuel combustion and agricultural sources. These findings show spatial and seasonal variation in N isotope data that reflect differences in sources of anthropogenic N deposition to high-elevation ecosystems and have important implications for environmental policy across the Rocky Mountain region.

Additional publication details

Publication type Article
Publication Subtype Journal Article
Title Spatial and temporal variation in sources of atmospheric nitrogen deposition in the Rocky Mountains using nitrogen isotopes
Series title Atmospheric Environment
DOI 10.1016/j.atmosenv.2017.12.023
Volume 176
Year Published 2018
Language English
Publisher Elsevier
Contributing office(s) Colorado Water Science Center
Description 10 p.
First page 110
Last page 119
Country United States
Other Geospatial Rocky Mountains