A predominantly shale and chert sequence has been mapped from the Canadian border at Latitude 65°00′ N. to the Nation River about 25 miles northwest. It has Ordovician and Silurian graptolites in the lower half, and Middle Devonian corals and Upper Devonian spores in the upper half.

The lower half of the sequence consists of about 400 to 900 feet of predominantly dark gray graptolitic shale with lesser amounts of grayish black laminated chert. This unit has been traced by Green and Roddick from the international border southeastward into the Dawson area of the Yukon Territory and northeastward into the Ogilvie and Richardson Mountains where it has been mapped by Jackson & Lenz, Norris, and others as the Road River Formation. In the Tatonduk-Nation Rivers area the Road River Formation rests disconformably on a sequence of Middle and Upper Cambrian limestone that locally may include Lower Ordovician (Tremadoc) beds at its top. The sequence of graptolite faunas from the Road River Formation in Alaska is essentially the same as the graptolite zones established by Elles and Wood in Great Britain. All the standard series of the Ordovician and Silurian are probably represented in the formation with the exception of the Tremadoc and possibly the Arenig and Wenlock.

Overlying the Road River Formation is a formation, 200 to 800 feet thick, consisting predominantly of thinly bedded and laminated light gray to black chert and siliceous shale that is here named the McCann Hill Chert. This new formation disconformably overlies the Road River Formation, and its lower boundary is at the base of a distinctive limestone and shale member. The basal limestone and shale member of the McCann Hill Chert contains a remarkably varied fauna including corals, brachiopods, trilobites, conodonts, ostracods, and fish of Eifelian (early Middle Devonian) age. Spores from the upper part of the formation resemble those from the overlying Nation River Formation and indicate a Late Devonian age. The McCann Hill Chert is conformably overlain by the Nation River Formation—a thick succession of inter-bedded graywacke, chert conglomerate, and silty shale of Late Devonian age.

In the vicinity of Jones Ridge, only 7 miles north of exposures of the Road River Formation, Upper Cambrian limestone is overlain by a pure limestone section containing Ordovician, Middle Devonian, and perhaps Silurian shelly faunas contemporaneous with the Road River Formation and the thinner basal limestone and shale member of the McCann Hill Chert. The rapid change from graptolitic shale to limestone probably reflects changes in conditions of sedimentation, but could be a result of thrust faulting.

The Tatonduk-Nation Rivers area seems to lie in a transitional zone between an early Paleozoic eugeosynclinal belt south of the Yukon River and a contemporaneous miogeosynclinal belt along the Porcupine River. One puzzling feature of the lower Paleozoic sequence in the Tatonduk-Nation Rivers area is its thinness in contrast to the much thicker volcanic and detrital sequence on the south and the considerably thicker carbonate sequence on the north.