Mass spectrometric in the analysis of inorganic substances

Edited by: Robert A. Meyers



Mass spectrometry is an analytical technique used to measure the composition of a substance by isolating specific analyte components according to their individual atomic or molecular mass‐to‐charge ratios. Inorganic mass spectrometry is specifically used to determine the elemental and isotopic composition of the material being analyzed. The techniques are capable of the measurement of a range of concentrations from major components to ultratrace constituents. Several instrumental approaches are used to separate and measure the abundance of component ions formed from the sample. These techniques include electron ionization mass spectrometry (EIMS), inductively coupled plasma mass spectrometry (ICPMS), thermal ionization mass spectrometry (TIMS) and spark source mass spectrometry (SSMS). These techniques utilize a variety of mass spectrometers including ion trap, quadrupole, magnetic sector and time‐of‐flight mass analyzers, depending on the type of sample being analyzed and the desired quality of the results. Often sample introduction techniques can be utilized to enhance the capabilities for solving specific analytical chemistry problems.

Additional publication details

Publication type Book chapter
Publication Subtype Book Chapter
Title Mass spectrometric in the analysis of inorganic substances
DOI 10.1002/9780470027318.a6010
Year Published 2006
Language English
Publisher Wiley
Contributing office(s) Toxic Substances Hydrology Program, National Research Program - Central Branch
Description 13 p.
Larger Work Type Book
Larger Work Title Encyclopedia of analytical chemistry: Applications, theory and instrumentation
First page 11761
Last page 11773