C–O stable isotope geochemistry and 40Ar/39Ar geochronology of the Bear Lodge carbonatite stockwork, Wyoming, USA

LITHOS
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Abstract

The carbonatite dike swarm and vein stockwork at the center of the Paleogene Bear Lodge alkaline complex (BLAC), Wyoming, USA, is host to diverse REE mineral assemblages that are largely a result of subsolidus modification and REE redistribution. Pseudomorphic replacement of primary burbankite by an assemblage of ancylite, strontianite, and barite is the result of interaction with late-stage hydrothermal fluids that added Sr, Ba, S, F, and REE, analogous to the replacement processes described for some carbonatite complexes of Russia's Kola Peninsula. Carbon and oxygen stable isotope ratios indicate that the primary carbonatite mineralogy experienced degassing/pneumatolysis and alteration by fluids of variable temperature, CO2/H2O ratios, and/or meteoric water content. Isotopic differences of matrix calcite between Group 1 carbonatites (avg. δ13C = −7.3‰; δ18O = 9.1‰) and Group 2 carbonatites (avg. δ13C = −9.9‰; δ18O = 10.2‰) are consistent with loss of CO2 during degassing. The open-system alteration of burbankite caused a pronounced positive δ18O-shift in bulk ancylite pseudomorphs (δ18O: 14.3–25.7‰) relative to matrix calcite (δ18O: 8.7–11.2‰). Oxygen isotope compositions of biotite (δ18O: 4.5–5.9‰) and K-feldspar (δ18O: 7.3–7.9‰) in unoxidized carbonatite are typical of primary magmatic silicates and suggest that fluids responsible for the burbankite-to-ancylite conversion remained predominantly magmatic (carbohydrothermal). Concomitant increases toward the surface in 13C and 18O, oxidation, matrix carbonate dissolution, and the replacement of REE carbonates (ancylite, carbocernaite, and burbankite) by Ca-REE fluorocarbonates (bastnäsite, parisite, synchysite) suggest interaction with late-stage, low temperature (<250 °C) fluids characterized by lower CO2/H2O ratios, and an increasing meteoric water component. The first 40Ar/39Ar ages from carbonatite-hosted biotite and K-feldspar at the BLAC are between 51.45 ± 0.08 and 51.89 ± 0.14 Ma. Although carbonatite is commonly observed as the final intrusive phase in alkaline igneous complexes, relative-age relationships and previously published geochronology for Bear Lodge rocks indicate that alkaline silicate magmatism both preceded and followed carbonatite emplacement.

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Additional publication details

Publication type Article
Publication Subtype Journal Article
Title C–O stable isotope geochemistry and 40Ar/39Ar geochronology of the Bear Lodge carbonatite stockwork, Wyoming, USA
Series title LITHOS
DOI 10.1016/j.lithos.2018.11.030
Volume 324-324
Year Published 2019
Language English
Publisher Elsevier
Contributing office(s) Geology, Minerals, Energy, and Geophysics Science Center
Description 21 p.
First page 640
Last page 660
Country United States
State Wyoming
Other Geospatial Bear Lodge alkaline complex
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